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1

Les ligands à base d'éléments du groupe principal en catalyse et en chimie de coordination: Main-group ligands in catalysis and coordination chemistry

Pascal Le Floch, Robert Crabtree

Journal:

Comptes Rendus Chimie

Year:

2004

Language:

french

File:

PDF, 111 KB

french, 2004

2

Synthesis, X-Ray, and Electronic Structures of a New Nickel Dibromide Complex. Activity in the Regioselective Catalyzed Dimerization of Ethylene into 1-Butene

Mora, Guilhem, van Zutphen, Steven, Klemps, Christian, Ricard, Louis, Jean, Yves, Le Floch, Pascal

Journal:

Inorganic Chemistry

Year:

2007

Language:

english

File:

PDF, 248 KB

english, 2007

3

Palladium(0)-Catalyzed Trimerization of Arylisocyanates into 1,3,5-Triarylisocyanurates in the Presence of Diimines: A Nonintuitive Mechanism

Paul, Frédéric, Moulin, Solenne, Piechaczyk, Olivier, Le Floch, Pascal, Osborn, John A.

Journal:

Journal of the American Chemical Society

Year:

2007

Language:

english

File:

PDF, 401 KB

english, 2007

4

Thermal conversion of 1-alkynyl-1,2-dihydrophosphetes into phosphinines

Narcis Avarvari, Pascal Le Floch, Claude Charrier, François Mathey

Journal:

Heteroatom Chemistry

Year:

1996

Language:

english

File:

PDF, 481 KB

english, 1996

5

[(Arene)(Diene)Fe] and [(Arene)(Diazadiene)Fe] Complexes: Preparation, Reactivity, and Catalytic Properties

Pascal Le Floch, Falk Knoch, Frank Kremer, Francois Mathey, Joachim Scholz, Wolfgang Scholz, Karl-Heinz Thiele, Ulrich Zenneck

Journal:

European Journal of Inorganic Chemistry

Year:

1998

Language:

english

File:

PDF, 449 KB

english, 1998

6

Synthesis, X-ray Crystal Structures and Reactivity Towards Alkynes of Gold(I)–Phosphinine Complexes

Nicolas Mézailles, Louis Ricard, François Mathey, Pascal Le Floch

Journal:

European Journal of Inorganic Chemistry

Year:

1999

Language:

english

File:

PDF, 396 KB

english, 1999

7

Unprecedented Coordination of 4,4′,5,5′-Tetramethyl-2,2′-biphosphinine Doubly Bridging over an Open Triosmium Core

Maarten J. Bakker, Frank W. Vergeer, František Hartl, Kees Goubitz, Jan Fraanje, Patrick Rosa, Pascal Le Floch

Journal:

European Journal of Inorganic Chemistry

Year:

2000

Language:

english

File:

PDF, 200 KB

english, 2000

8

Diels-Alder Reactions of tert-Butylphosphaethyne with 1,3,2-Diaza- and 1,2-Azaphosphinines

Narcis Avarvari, Louis Ricard, François Mathey, Pascal Le Floch, Oliver Löber, Manfred Regitz

Journal:

European Journal of Organic Chemistry

Year:

1998

Language:

english

File:

PDF, 363 KB

english, 1998

9

Gold(I)- und Gold(0)-Komplexe mit Makrocyclen auf Phosphininbasis

Nicolas Mézailles, Narcis Avarvari, Nicole Maigrot, Louis Ricard, François Mathey, Pascal Le Floch, Laurent Cataldo, Théo Berclaz, Michel Geoffroy

Journal:

Angewandte Chemie

Year:

1999

Language:

german

File:

PDF, 115 KB

german, 1999

10

Dianionic Homoleptic Biphosphinine Complexes of Group 4 Metals

Patrick Rosa, Nicolas Mézailles, Louis Ricard, François Mathey, Pascal Le Floch

Journal:

Angewandte Chemie

Year:

2000

Language:

english

File:

PDF, 139 KB

english, 2000

11

Synthesis and X-ray Crystal Structures of Silacalix[n]phosphinines: The First sp2-Based Phosphorus Macrocycles

Narcis Avarvari, Nicole Maigrot, Louis Ricard, François Mathey, Pascal Le Floch

Journal:

Chemistry - A European Journal

Year:

1999

Language:

english

File:

PDF, 295 KB

english, 1999

12

Gold(I) and Gold(0) Complexes of Phosphinine-Based Macrocycles

Nicolas Mézailles, Narcis Avarvari, Nicole Maigrot, Louis Ricard, François Mathey, Pascal Le Floch, Laurent Cataldo, Théo Berclaz, Michel Geoffroy

Journal:

Angewandte Chemie International Edition

Year:

1999

Language:

english

File:

PDF, 126 KB

english, 1999

13

Dianionic Homoleptic Biphosphinine Complexes of Group 4 Metals

Patrick Rosa, Nicolas Mézailles, Louis Ricard, François Mathey, Pascal Le Floch

Journal:

Angewandte Chemie International Edition

Year:

2000

Language:

english

File:

PDF, 143 KB

english, 2000

14

Syntheses of Phosphinine-Based Tripodal Ligands

Ute Rhörig, Nicolas Mézailles, Nicole Maigrot, Louis Ricard, François Mathey, Pascal Le Floch

Journal:

European Journal of Inorganic Chemistry

Year:

2000

Language:

english

File:

PDF, 351 KB

english, 2000

15

Synthesis and Reactivity Towards Cationic Group 11 Metal Centers of an Extended Silacalix-[3]-phosphinine Macrocycle

Audrey Moores, Nicolas Mézailles, Nicole Maigrot, Louis Ricard, François Mathey, Pascal le Floch

Journal:

European Journal of Inorganic Chemistry

Year:

2002

Language:

english

File:

PDF, 132 KB

english, 2002

16

Dianionic Iron and Ruthenium(2−) Biphosphinine Complexes: A Formal d10 Ruthenium Complex with a Square Planar Geometry

Patrick Rosa, Nicolas Mézailles, Louis Ricard, François Mathey, Pascal Le Floch, Yves Jean

Journal:

Angewandte Chemie

Year:

2001

Language:

english

File:

PDF, 95 KB

english, 2001

17

The tmbp Dianion in the Contact Ion Pair [(tmbp)Na2(dme)1.5]n and in the Solvent-Separated Ion Pair [tmbp][(2.2.1)Li]2

Patrick Rosa, Nicolas Mézailles, Louis Ricard, François Mathey, Pascal Le Floch

Journal:

Angewandte Chemie

Year:

2001

Language:

english

File:

PDF, 165 KB

english, 2001

18

Di- and Tetranuclear Palladium Complexes Incorporating Phospha- and Diphosphaferrocenes as Ligands

Xavier Sava, Louis Ricard, François Mathey, Pascal Le Floch

Journal:

Chemistry - A European Journal

Year:

2001

Language:

english

File:

PDF, 166 KB

english, 2001

19

Bonding and Redox Properties of [Os3(CO)9(tmbp)(L)] (tmbp=4,4′,5,5′-tetramethyl-2,2′-biphosphinine; L=CO, PPh3) Clusters with an Unprecedented Electron-Deficient Metallic Core and Doubly Bridging Biphosphinine Dianion

Maarten J. Bakker, Frank W. Vergeer, František Hartl, Patrick Rosa, Louis Ricard, Pascal Le Floch, Maria J. Calhorda

Journal:

Chemistry - A European Journal

Year:

2002

Language:

english

File:

PDF, 260 KB

english, 2002

20

Dianionic Iron and Ruthenium(2−) Biphosphinine Complexes: A Formal d10 Ruthenium Complex with a Square Planar Geometry

Patrick Rosa, Nicolas Mézailles, Louis Ricard, François Mathey, Pascal Le Floch, Yves Jean

Journal:

Angewandte Chemie International Edition

Year:

2001

Language:

english

File:

PDF, 95 KB

english, 2001

21

The tmbp Dianion in the Contact Ion Pair [(tmbp)Na2(dme)1.5]n and in the Solvent-Separated Ion Pair [tmbp][(2.2.1)Li]2

Patrick Rosa, Nicolas Mézailles, Louis Ricard, François Mathey, Pascal Le Floch

Journal:

Angewandte Chemie International Edition

Year:

2001

Language:

english

File:

PDF, 142 KB

english, 2001

22

Umsetzung von weißem Phosphor mit Lithium(trimethylsilyl)diazomethanid zu einem 1, 2, 3, 4-Diazadiphosphol: ein direkter Zugang zu einem neuen, aromatischen Ringsystem

Dr. Claude Charrier, Nicol Maygrot, Dr. Louis Ricard, Dr. Pascal Le Floch, Prof. Dr. François Mathey

Journal:

Angewandte Chemie

Year:

1996

Language:

german

File:

PDF, 269 KB

german, 1996

23

A 1-Methyl-Phosphininium Compound: Synthesis, X-Ray Crystal Structure, and DFT Calculations

Audrey Moores, Louis Ricard, Pascal Le Floch

Journal:

Angewandte Chemie

Year:

2003

Language:

english

File:

PDF, 143 KB

english, 2003

24

A Bis(thiophosphinoyl)methanediide Palladium Complex: Coordinated Dianion or Nucleophilic Carbene Complex?

Thibault Cantat, Nicolas Mézailles, Louis Ricard, Yves Jean, Pascal Le Floch

Journal:

Angewandte Chemie

Year:

2004

Language:

english

File:

PDF, 158 KB

english, 2004

25

Heterolytische Wasserstoffspaltung mit Rhodium(I)-amiden

Pascal Maire, Torsten Büttner, Frank Breher, Pascal Le Floch, Hansjörg Grützmacher

Journal:

Angewandte Chemie

Year:

2005

Language:

german

File:

PDF, 170 KB

german, 2005

26

Formation and Structure of a Stable Monoradical Cation by Reduction of a Diphosphafulvenium Salt

Frédéric Biaso, Thibault Cantat, Nicolas Mézailles, Louis Ricard, Pascal Le Floch, Michel Geoffroy

Journal:

Angewandte Chemie

Year:

2006

Language:

english

File:

PDF, 167 KB

english, 2006

27

From a Stable Dianion to a Stable Carbenoid

Thibault Cantat, Xavier Jacques, Louis Ricard, Xavier Frédéric Le Goff, Nicolas Mézailles, Pascal Le Floch

Journal:

Angewandte Chemie

Year:

2007

Language:

english

File:

PDF, 159 KB

english, 2007

28

The Reaction of White Phosphorus with Lithium (Trimethylsilyl)diazomethanide: Direct Access to a New, Aromatic 1,2,3,4-Diazadiphosphole Ring

Dr. Claude Charrier, Nicole Maigrot, Dr. Louis Ricard, Dr. Pascal Le Floch, Prof. Dr. François Mathey

Journal:

Angewandte Chemie International Edition

Year:

1996

Language:

english

File:

PDF, 261 KB

english, 1996

29

A 1-Methyl-Phosphininium Compound: Synthesis, X-Ray Crystal Structure, and DFT Calculations

Audrey Moores, Louis Ricard, Pascal Le Floch

Journal:

Angewandte Chemie International Edition

Year:

2003

Language:

english

File:

PDF, 144 KB

english, 2003

30

A Bis(thiophosphinoyl)methanediide Palladium Complex: Coordinated Dianion or Nucleophilic Carbene Complex?

Thibault Cantat, Nicolas Mézailles, Louis Ricard, Yves Jean, Pascal Le Floch

Journal:

Angewandte Chemie International Edition

Year:

2004

Language:

english

File:

PDF, 159 KB

english, 2004

31

Heterolytic Splitting of Hydrogen with Rhodium(I) Amides

Pascal Maire, Torsten Büttner, Frank Breher, Pascal Le Floch, Hansjörg Grützmacher

Journal:

Angewandte Chemie International Edition

Year:

2005

Language:

english

File:

PDF, 172 KB

english, 2005

32

Formation and Structure of a Stable Monoradical Cation by Reduction of a Diphosphafulvenium Salt

Frédéric Biaso, Thibault Cantat, Nicolas Mézailles, Louis Ricard, Pascal Le Floch, Michel Geoffroy

Journal:

Angewandte Chemie International Edition

Year:

2006

Language:

english

File:

PDF, 168 KB

english, 2006

33

From a Stable Dianion to a Stable Carbenoid

Thibault Cantat, Xavier Jacques, Louis Ricard, Xavier Frédéric Le Goff, Nicolas Mézailles, Pascal Le Floch

Journal:

Angewandte Chemie International Edition

Year:

2007

Language:

english

File:

PDF, 159 KB

english, 2007

34

Phosphorus Analogs of Bipyridines: Their Synthesis and Coordination Chemistry

François Mathey, Pascal Le Floch

Journal:

European Journal of Inorganic Chemistry

Year:

1996

Language:

english

File:

PDF, 460 KB

english, 1996

35

2-Phosphanylphosphinines as Bridging Ligands for Dinuclear Transition Metal Carbonyls

Klaus Waschbüch, Pascal Le Floch, Louis Ricard, François Mathey

Journal:

European Journal of Inorganic Chemistry

Year:

1997

Language:

english

File:

PDF, 896 KB

english, 1997

36

Effect of Conformational Changes on a One-Electron Reduction Process: Evidence of a One-Electron PP Bond Formation in a Bis(phosphinine)

Sylvie Choua, Cosmina Dutan, Laurent Cataldo, Théo Berclaz, Michel Geoffroy, Nicolas Mézailles, Audrey Moores, Louis Ricard, Pascal Le Floch

Journal:

Chemistry - A European Journal

Year:

2004

Language:

english

File:

PDF, 365 KB

english, 2004

37

New Hybrid Bidentate Ligands as Precursors for Smart Catalysts

Frédéric Goettmann, Cédric Boissière, David Grosso, François Mercier, Pascal Le Floch, Clément Sanchez

Journal:

Chemistry - A European Journal

Year:

2005

Language:

english

File:

PDF, 435 KB

english, 2005

38

2,2′-Biphosphinines and 2,2′-Bipyridines in Homoleptic Dianionic Group 4 Complexes and Neutral 2,2′-Biphosphinine Group 6 d6 Metal Complexes: Octahedral versus Trigonal-Prismatic Geometries

Hervé Lesnard, Thibault Cantat, Pascal Le Floch, Isabelle Demachy, Yves Jean

Journal:

Chemistry - A European Journal

Year:

2007

Language:

english

File:

PDF, 502 KB

english, 2007

39

Why Platinum Catalysts Involving Ligands with Large Bite Angle Are so Efficient in the Allylation of Amines: Design of a Highly Active Catalyst and Comprehensive Experimental and DFT Study

Guilhem Mora, Olivier Piechaczyk, Romaric Houdard, Nicolas Mézailles, Xavier-Frederic Le Goff, Pascal le Floch

Journal:

Chemistry - A European Journal

Year:

2008

Language:

english

File:

PDF, 462 KB

english, 2008

40

Cobalt-Catalyzed Formation of Symmetrical Biaryls and Its Mechanism

Aurélien Moncomble, Pascal Le Floch, Corinne Gosmini

Journal:

Chemistry - A European Journal

Year:

2009

Language:

english

File:

PDF, 235 KB

english, 2009

41

PCNCP Ligands in the Chromium-Catalyzed Oligomerization of Ethylene: Tri- versus Tetramerization

Christian Klemps, Elina Payet, Lionel Magna, Lucien Saussine, Xavier F. Le Goff, Pascal Le Floch

Journal:

Chemistry - A European Journal

Year:

2009

Language:

english

File:

PDF, 434 KB

english, 2009

42

Double Friedel–Crafts Acylation Reactions on the Same Ring of a Metallocene: Synthesis of a 2,5-Diacetylphospharuthenocene

Dr. Duncan Carmichael, Prof. Dr. Pascal Le Floch, Dr. Xavier F. Le Goff, Dr. Olivier Piechaczyk, Dr. Nicolas Seeboth

Journal:

Chemistry - A European Journal

Year:

2010

Language:

english

File:

PDF, 667 KB

english, 2010

43

P4 Activation with Pt0 Metal Centers: Selective Formation of a Dinuclear {Pt2(μ,η2:2-P2)} Complex

Matthieu Demange, Dr. Xavier-Frédéric Le Goff, Prof. Dr. Pascal Le Floch, Dr. Nicolas Mézailles

Journal:

Chemistry - A European Journal

Year:

2010

Language:

english

File:

PDF, 253 KB

english, 2010

44

Mechanism of the Dehydrogenative Silylation of Alcohols Catalyzed by Cationic Gold Complexes: An Experimental and Theoretical Study

Stéphanie Labouille, Aurélie Escalle-Lewis, Prof. Yves Jean, Dr. Nicolas Mézailles, Prof. Pascal Le Floch

Journal:

Chemistry - A European Journal

Year:

2011

Language:

english

File:

PDF, 497 KB

english, 2011

45

ChemInform Abstract: Transition Metals in Phosphinine Chemistry

Pascal Le Floch, Francois Mathey

Journal:

Year:

1999

File:

PDF, 22 KB

1999

46

ChemInform Abstract: Synthesis of Functional 1,4-Diphosphaindenes and Their Related Anions.

Patrick Rosa, Louis Ricard, Francois Mathey, Pascal Le Floch

Journal:

Year:

1999

File:

PDF, 32 KB

1999

47

ChemInform Abstract: New Carbon—Phosphorus Macrocycles

Francois Mathey, Francois Mercier, Pascal Le Floch

Journal:

Year:

2000

File:

PDF, 23 KB

2000

48

ChemInform Abstract: Bis(diphosphaferrocene) Palladium(II) Dimer Complexes as Efficient Catalysts in the Synthesis of Arylboronic Esters.

Mohand Melaimi, Francois Mathey, Pascal Le Floch

Journal:

Year:

2002

File:

PDF, 29 KB

2002

49

ChemInform Abstract: Six-Membered Rings: Phosphinines

Pascal Le Floch

Journal:

Year:

2002

File:

PDF, 22 KB

2002

50

ChemInform Abstract: The Coordination Chemistry of Phosphinines: Their Polydentate and Macrocyclic Derivatives

Nicolas Mezailles, Francois Mathey, Pascal Le Floch

Journal:

Year:

2002

File:

PDF, 22 KB

2002

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